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Mn sup 2+ /sup -doped CsPbBr sub 3 /sub perovskite supercrystals: enhancing morphology and substrate variation

Author(s): Lapointe V; Majewski MB;

The self-assembly of metal halide perovskite nanocrystals into micrometer-sized supercrystals with a high structural order as influenced by the surface chemistry and particle morphology of the starting building blocks is of interest for a broad spectrum of applications. In this work, we investigated the effects of Mn2+-doping CsPbBr3 perovskite nanocrys ...

Article GUID: 41190408


Manganese-enriched CsPbCl3 perovskite nanocrystals for self-assembled supercrystals

Author(s): Lapointe V; Majewski MB;

The self-assembly of CsPbCl3 perovskite nanocrystals and their Mn2+-enriched analogs into supercrystals is reported. Increasing Mn2+ content in the nanocrystals leads to formation of larger, increasingly uniform cubic supercrystals that eventually become rod-like with higher photoluminescence quantum yields.

Article GUID: 39347586


A Modular and Catalytic Methodology To Access 2,5-Furan-Based Phenylene/Thiophene Oligomers through a One-Pot Decarboxylative Cross-Coupling from 5-Bromofurfural

Author(s): Cigana B; Lapointe V; Majewski MB; Forgione P;

A library of 2,5-furan-based phenylene/thiophene oligomers were synthesized starting from 5-bromofurfural, a derivative of biomass-derived furfural. Varied electronic groups are coupled onto the furan motif, followed by the installation of a phenylene or thiophene central linker through a one-pot Pd-catalyzed decarboxylative cross-coupling reaction. Res ...

Article GUID: 38808994


Long live(d) CsPbBr3 superlattices: colloidal atomic layer deposition for structural stability

Author(s): Lapointe V; Green PB; Chen AN; Buonsanti R; Majewski MB;

Superlattice formation afforded by metal halide perovskite nanocrystals has been a phenomenon of interest due to the high structural order induced in these self-assemblies, an order that is influenced by the surface chemistry and particle morphology of the starting building block material. In this work, we report on the formation of superlattices from a ...

Article GUID: 38516096


Virtual Reality Could Help Assess Sexual Aversion Disorder

Author(s): Lafortune D; Dubé S; Lapointe V; Bonneau J; Champoux C; Sigouin N;

Virtual reality (VR) may improve our understanding of sexual dysfunctions' manifestations, although research in this area remains limited. This study assessed the potential use of a VR Behavior Avoidance Test (VR-BAT) as a tool for examining the clinical features of Sexual Aversion Disorder (SAD): the experience of fear, disgust, and avoidance when ...

Article GUID: 37556729


Photonic enhancement in photoluminescent metal halide perovskite-photonic crystal bead hybrids

Author(s): Lapointe V; Imperiale CJ; Chengadu S; Pomilio CM; Ganesh M; Kéna-Cohen S; Majewski MB;

We report two photonic crystal-perovskite nanocrystal microbead hybrids with photoluminescence matching that of the parent nanocrystals but with increased photoluminescence quantum yields. Time-resolved photoluminescence spectroscopy quantifies the radiative enhancement afforded by the photonic environment of the microbeads. The reported hybrids also de ...

Article GUID: 37548908


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