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Photoluminescent Properties of Tb-UiO-66 Metal-Organic Framework Analogues

Author(s): Canales Gálvez XA; Richezzi M; Bicalho HA; Labadie N; Pellegrinet SC; Titi HM; Howarth AJ;

Three new analogues of Tb-UiO-66 with various functional groups (-F, -Br, -NH2) on the terephthalic acid linker of the metal-organic framework (MOF) are synthesized and characterized. The photoluminescent properties of these analogues, as well as Tb-UiO-66 and Tb-UiO-66-(OH)2, are studied and cor ...

Article GUID: 39849977


Rare-earth acetates as alternative precursors for rare-earth cluster-based metal-organic frameworks

Author(s): Richezzi M; Donnarumma PR; Copeman C; Howarth AJ;

RE-UiO-66 analogues are synthesized using RE acetates as precursors for the first time. These MOFs are fully characterized and the influence of the precursor on the materials obtained is studied. Additionally, the influence of water on the yield of the syntheses and the quality of the materials is explored.

Article GUID: 38646995


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