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Rare-earth acetates as alternative precursors for rare-earth cluster-based metal-organic frameworks

Author(s): Richezzi M; Donnarumma PR; Copeman C; Howarth AJ;

RE-UiO-66 analogues are synthesized using RE acetates as precursors for the first time. These MOFs are fully characterized and the influence of the precursor on the materials obtained is studied. Additionally, the influence of water on the yield of the synt ...

Article GUID: 38646995


Remodelling a shp: Transmetalation in a Rare-Earth Cluster-Based Metal-Organic Framework

Author(s): Bicalho HA; Donnarumma PR; Quezada-Novoa V; Titi HM; Howarth AJ;

Postsynthetic modification of metal-organic frameworks (MOFs) is an important strategy for accessing MOF analogues that cannot be easily synthesized de novo. In this work, the rare-earth (RE) cluster-based MOF Y-CU-10 with shp topology was modified through ...

Article GUID: 34314164


Synthetic approaches for accessing rare-earth analogues of UiO-66

Author(s): Donnarumma PR; Frojmovic S; Marino P; Bicalho HA; Titi HM; Howarth AJ;

Rare-earth (RE) analogues of UiO-66 with non-functionalised 1,4-benzenedicarboxylate linkers are synthesised for the first time, and a series of synthetic approaches is provided to troubleshoot the synthesis. RE-UiO-66 analogues are fully characterised, and ...

Article GUID: 34027524


Molecular Copper(I)-Copper(II) Photosensitizer-Catalyst Photoelectrode for Water Oxidation.

Author(s): Singh Z, Donnarumma PR, Majewski MB

Copper(II)-based electrocatalysts for water oxidation in aqueous solution have been studied previously, but photodriving these systems still remains a challenge. In this work, a bis(diimine)copper(I)-based donor-chromophore-acceptor system is synthesized an ...

Article GUID: 32909755


Rare-earth metal-organic frameworks: from structure to applications.

Author(s): Saraci F, Quezada-Novoa V, Donnarumma PR, Howarth AJ

Chem Soc Rev. 2020 Jul 13;: Authors: Saraci F, Quezada-Novoa V, Donnarumma PR, Howarth AJ

Article GUID: 32658241


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