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Mechanochemical Synthesis of Boroxine-linked Covalent Organic Frameworks

Author(s): Hamzehpoor E; Effaty F; Borchers TH; Stein RS; Wahrhaftig-Lewis A; Ottenwaelder X; Frišcic T; Perepichka DF; ...

We report a rapid, room-temperature mechanochemical synthesis of 2- and 3-dimensional boroxine covalent organic frameworks (COFs), enabled by using trimethylboroxine as a dehydrating additive to ov ...

Article GUID: 38970305


Resonant acoustic mixing (RAM) for efficient mechanoredox catalysis without grinding or impact media

Author(s): Effaty F; Gonnet L; Koenig SG; Nagapudi K; Ottenwaelder X; Frišcic T;

Resonant acoustic mixing (RAM) enables mechanoredox catalysis with BaTiO3 as the piezoelectric catalyst on model diazonium coupling reactions. RAM proceeds without formal grinding or impact media, is faster than the analogous ball-milling strategy, and is r ...

Article GUID: 36546478


Simplifying and expanding the scope of boron imidazolate framework (BIF) synthesis using mechanochemistry

Author(s): Lennox CB; Do JL; Crew JG; Arhangelskis M; Titi HM; Howarth AJ; Farha OK; Frišcic T;

Mechanochemistry enables rapid access to boron imidazolate frameworks (BIFs), including ultralight materials based on Li and Cu(i) nodes, as well as new, previously unexplored systems based on Ag(i) nodes. Compared to solution methods, mechanochemistry is f ...

Article GUID: 34881001


Simple, scalable mechanosynthesis of metal-organic frameworks using liquid-assisted resonant acoustic mixing (LA-RAM)

Author(s): Titi HM; Do JL; Howarth AJ; Nagapudi K; Frišcic T;

We present a rapid and readily scalable methodology for the mechanosynthesis of diverse metal-organic frameworks (MOFs) in the absence of milling media typically required for other types of mechanochemical syntheses. We demonstrate the use of liquid-assiste ...

Article GUID: 34094134


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