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Overlap and Covalency in a κN-Arylnitrosyl Cu(II) Metalloradical Formed by Hydroxylamine Oxidative Binding

Author(s): MacKay A; Zsombor-Pindera J; Effaty F; Sheibany N; Gennarini F; Habibian M; Chen F; Askari MS; Brytskyi M; Kroeker S; Kennepohl P; Ottenwaelder X;

Redox noninnocent ligands present opportunities to access reactive metal-radical complexes, but competing redox pathways often hinder their selective formation. Here, a pentadentate arylhydroxylamine-containing (ArNHOH) ligand directs copper salts to form a single, well-defined CuII-arylnitrosyl ...

Article GUID: 41524899


Tuning Inner-Sphere Electron Transfer in a Series of Copper/Nitrosoarene Adducts.

Author(s): Askari MS, Effaty F, Gennarini F, Orio M, Le Poul N, Ottenwaelder X

Inorg Chem. 2020 Feb 19;: Authors: Askari MS, Effaty F, Gennarini F, Orio M, Le Poul N, Ottenwaelder X

Article GUID: 32073833


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