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Mechanochemical synthesis of π-conjugated naphthotetrathiophene-based covalent organic frameworks and their post-modification em via /em the Doebner reaction

Author(s): Gohari MH; Ghamari P; Hamzehpoor E; Effaty F; Frišcic T; Perepichka DF;

We report that mechanochemistry enables the synthesis of new p-conjugated covalent organic frameworks (COFs) based on naphthotetrathiophenetetracarbaldehydes 2TTN and 3TTN, expanding the scope of COF structures with two new isomeric tetradentate nodes. While recent studies have explored COF isomerism by varying bidentate linkers to tune electronic propert ...

Article GUID: 40936612


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