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A Modular and Catalytic Methodology To Access 2,5-Furan-Based Phenylene/Thiophene Oligomers through a One-Pot Decarboxylative Cross-Coupling from 5-Bromofurfural

Author(s): Cigana B; Lapointe V; Majewski MB; Forgione P;

A library of 2,5-furan-based phenylene/thiophene oligomers were synthesized starting from 5-bromofurfural, a derivative of biomass-derived furfural. Varied electronic groups are coupled onto the furan motif, followed by the installation of a phenylene or th ...

Article GUID: 38808994


Long live(d) CsPbBr3 superlattices: colloidal atomic layer deposition for structural stability

Author(s): Lapointe V; Green PB; Chen AN; Buonsanti R; Majewski MB;

Superlattice formation afforded by metal halide perovskite nanocrystals has been a phenomenon of interest due to the high structural order induced in these self-assemblies, an order that is influenced by the surface chemistry and particle morphology of the ...

Article GUID: 38516096


Effects of increasing ligand conjugation in Cu(I) photosensitizers on NiO semiconductor surfaces

Author(s): Singh Z; Chiong JD; Kamal S; Majewski MB;

Dye-sensitized photoelectrodes may be used as heterogeneous components for fuel-forming reactions in photoelectrochemical cells. There has been increasing interest in developing Earth-abundant cheaper photosensitizers based on first-row transition metals. W ...

Article GUID: 38497406


Photonic enhancement in photoluminescent metal halide perovskite-photonic crystal bead hybrids

Author(s): Lapointe V; Imperiale CJ; Chengadu S; Pomilio CM; Ganesh M; Kéna-Cohen S; Majewski MB;

We report two photonic crystal-perovskite nanocrystal microbead hybrids with photoluminescence matching that of the parent nanocrystals but with increased photoluminescence quantum yields. Time-resolved photoluminescence spectroscopy quantifies the radiativ ...

Article GUID: 37548908


Binary Cu2-xS Templates Direct the Formation of Quaternary Cu2ZnSnS4 (Kesterite, Wurtzite) Nanocrystals

Author(s): Yarur Villanueva F; Green PB; Qiu C; Ullah SR; Buenviaje K; Howe JY; Majewski MB; Wilson MWB; ...

Kesterite Cu2ZnSnS4 (k-CZTS) nanocrystals have received attention for their tunable optoelectronic properties, as well as the earth abundance of their constituent atoms. However, the phase-pure syn ...

Article GUID: 34705409


A historical perspective on porphyrin-based metal-organic frameworks and their applications

Author(s): Zhang X; Wasson MC; Shayan M; Berdichevsky EK; Ricardo-Noordberg J; Singh Z; Papazyan EK; Castro AJ; Marino P; Ajoyan Z; Chen Z; Islamoglu T ...

Porphyrins are important molecules widely found in nature in the form of enzyme active sites and visible light absorption units. Recent interest in using these functional molecules as building bloc ...

Article GUID: 33678810


Molecular Copper(I)-Copper(II) Photosensitizer-Catalyst Photoelectrode for Water Oxidation.

Author(s): Singh Z, Donnarumma PR, Majewski MB

Copper(II)-based electrocatalysts for water oxidation in aqueous solution have been studied previously, but photodriving these systems still remains a challenge. In this work, a bis(diimine)copper(I)-based donor-chromophore-acceptor system is synthesized an ...

Article GUID: 32909755


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