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Intramolecular H-bond stabilization of a primary hydroxylamine in salen-type metal complexes

Author(s): Singh H; MacKay A; Sheibany N; Chen F; Mosser M; Rouet PÉ; Rousseau F; Askari MS; Ottenwaelder X; ...

Primary hydroxylamines, RNHOH, decompose readily in the presence of transition metal ions. We show that this reactivity can be arrested by ligand design via an intramolecular hydrogen bond. Six met ...

Article GUID: 34545379


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