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Stability of Acetals/Ketals Under Controlled Radical and Ring Opening Polymerization

Author(s): Andrade-Gagnon B; Casillas-Popova SN; Oh JK;

Well-defined acid-degradable amphiphilic block copolymers (ABPs) and their nanoassemblies labeled with acid-labile groups have been developed for smart drug delivery, exhibiting controlled/enhanced release of therapeutics in tumoral tissues and endo/lysosomes. In general, controlled polymerization techniques, particularly atom transfer radical polymerizat ...

Article GUID: 40614241


Enhanced biodegradation of crude oil by phosphate-solubilizing bacteria Bacillus subtilis PSB-1: Overcoming soluble phosphorus deficiency

Author(s): Wang X; Du Z; Li Z; Liu M; Mu J; Feng L; Chen Z; Chen Q;

Due to the oligotrophic marine environment, the lack of phosphorus is one of the key factors limiting the oil biodegradation ability of microorganisms after the oil spill occurs. Overcoming phosphorus deficiency has become an urgent problem. In this study, a phosphate-solubilizing bacteria, named Bacillus subtilis PSB-1, with the crude oil degradation eff ...

Article GUID: 40609441


Application of machine learning for predicting the incubation period of water droplet erosion in metals

Author(s): AlHammad K; Medraj M; Tembely M;

Water droplet erosion (WDE) is a critical degradation phenomenon that significantly affects component lifespan and performance in power generation, aerospace, and wind energy industries. The incubation period-the initial phase before visible material loss occurs-is particularly crucial for maintenance planning and material selection yet remains challengin ...

Article GUID: 40612685


Konjac glucomannan (KGM) aerogel immobilized microalgae: A new way for marine oil spills remediation

Author(s): Wang X; Du Z; Song Z; Liu M; He P; Feng L; Chen Z; Chen Q;

This study investigated the oil pollution remediation ability of konjac glucomannan (KGM) aerogel immobilized Chlorella vulgaris LH-1 (C. vulgaris). The KGM aerogel exhibited a high porosity of 86.83 %, and with the change of crude oil concentration (1-10 g/L), the crude oil adsorption efficiency of KGM aerogel was up to 18.75 %. The KGM aerogel carrier e ...

Article GUID: 40381443


Photocatalytic innovations in PFAS removal: Emerging trends and advances

Author(s): Tabatabaei M; Cho DW; Fahad S; Jeong DW; Hwang JH;

Per- and polyfluoroalkyl substances (PFAS), such as perfluorooctanoic acid (PFOA) and perfluorooctanesulfonic acid (PFOS), are persistent environmental pollutants posing significant risks to ecosystems, drinking water safety, and human health. Conventional PFAS removal methods effectively mitigate contamination but face challenges such as high operational ...

Article GUID: 40315548


Radiation tolerance and biodegradation performance of a marine bacterium Acinetobacter sp. Y9 in radioactive composite oil-contaminated wastewater

Author(s): Yan J; Luo Q; Zhu B; Chen Z; Chen Q;

The tolerance and degradation characteristics of a marine oil-degrading strain Acinetobacter sp. Y9 were investigated in the presence of diesel oil and simulated radioactive nuclides (Mn2+, Co2+, Ni2+, Sr2+, Cs+) at varying concentrations, as well as exposure to ?-ray radiation (Co-60). The maximum tolerable concentrations for Co2+and Ni2+ were found to b ...

Article GUID: 39806541


Insights from multiple stable isotopes (C, N, Cl) into the photodegradation of herbicides atrazine and metolachlor

Author(s): Levesque-Vargas M; Ohlund L; Sleno L; Gélinas Y; Höhener P; Ponsin V;

Many processes can contribute to the attenuation of the frequently detected and toxic herbicides atrazine and metolachlor in surface water, including photodegradation. Multi-element compound-specific isotope analysis has the potential to decipher between these different degradation pathways as Cl is a promising tool for both pathway identification and a s ...

Article GUID: 39716600


The degradation of polylactic acid face mask components in different environments

Author(s): Lyu L; Bagchi M; Ng KTW; Markoglou N; Chowdhury R; An C; Chen Z; Yang X;

The disposal of fossil fuel-based plastics poses a huge environmental challenge, leading to increased interest in biodegradable alternatives such as polylactic acid (PLA). This study focuses on the environmental impact and degradation of PLA face mask components under various conditions (UV (Ultraviolet) radiation, DI water, landfill leachate of various a ...

Article GUID: 39378804


pH-Responsive Degradable Electro-Spun Nanofibers Crosslinked via Boronic Ester Chemistry for Smart Wound Dressings

Author(s): Casillas-Popova SN; Lokuge ND; Andrade-Gagnon B; Chowdhury FR; Skinner CD; Findlay BL; Oh JK;

Recent advances in the treatment of chronic wounds have focused on the development of effective strategies for cutting-edge wound dressings based on nanostructured materials, particularly biocompatible poly(vinyl alcohol) (PVA)-based electro-spun (e-spun) nanofibers. However, PVA nanofibers need ...

Article GUID: 38989606


Design, Synthesis, and Acid-Responsive Disassembly of Shell-Sheddable Block Copolymer Labeled with Benzaldehyde Acetal Junction

Author(s): Andrade-Gagnon B; Casillas-Popova SN; Jazani AM; Oh JK;

Smart nanoassemblies degradable through the cleavage of acid-labile linkages have attracted significant attention because of their biological relevance found in tumor tissues. Despite their high potential to achieve controlled/enhanced drug release, a systematic understanding of structural factors that affect their pH sensitivity remains challenging, part ...

Article GUID: 38499007


Janus Micromotors for Photophoretic Motion and Photon Upconversion Applications Using a Single Near-Infrared Wavelength

Author(s): Mena-Giraldo P; Kaur M; Maurizio SL; Mandl GA; Capobianco JA;

External stimuli can trigger changes in temperature, concentration, and momentum between micromotors and the medium, causing their propulsion and enabling them to perform different tasks with improved kinetic efficiencies. Light-activated micromotors are attractive systems that achieve improved motion and have the potential for high spatiotemporal control ...

Article GUID: 38197400


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