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High-Resolution Frequency-Domain Spectroscopic and Modeling Studies of Photosystem I (PSI), PSI Mutants and PSI Supercomplexes

Author(s): Zazubovich V; Jankowiak R;

Photosystem I (PSI) is one of the two main pigment-protein complexes where the primary steps of oxygenic photosynthesis take place. This review describes low-temperature frequency-domain experiments (absorption, emission, circular dichroism, resonant and no ...

Article GUID: 38612659


Superhydrophilic CoFe Dispersion of Hydrogel Electrocatalysts for Quasi-Solid-State Photoelectrochemical Water Splitting

Author(s): Wang H; Gao RT; Nguyen NT; Bai J; Ren S; Liu X; Zhang X; Wang L;

Photoelectrochemical (PEC) water splitting is an attractive strategy to convert solar energy to hydrogen. However, the lifetime of PEC devices is restricted by the photocorrosion of semiconductors and the instability of co-catalysts. Herein, we report a fea ...

Article GUID: 37901939


Sterically-Hindered Molecular p-Dopants Promote Integer Charge Transfer in Organic Semiconductors

Author(s): Charoughchi S; Liu JT; Berteau-Rainville M; Hase H; Askari MS; Bhagat S; Forgione P; Salzmann I; ...

Molecular p-dopants designed to undergo electron transfer with organic semiconductors are typically planar molecules with high electron affinity. However, their planarity can promote the formation ...

Article GUID: 37220083


The Effect of Linker-to-Metal Energy Transfer on the Photooxidation Performance of an Isostructural Series of Pyrene-Based Rare-Earth Metal-Organic Frameworks

Author(s): Quezada-Novoa V; Titi HM; Villanueva FY; Wilson MWB; Howarth AJ;

The tetratopic linker, 1,3,6,8-tetrakis(p-benzoic acid)pyrene (H4 TBAPy) along with rare-earth (RE) ions is used for the synthesis of 9 isostructures of a metal-organic framework (MOF) with shp topology, named RE-CU-10 (RE = Y(III), Gd(III), Tb(III), Dy(III ...

Article GUID: 37116124


Compatible-domain Transfer Learning for Breast Cancer Classification with Limited Annotated Data

Author(s): Shamshiri MA; Krzyzak A; Kowal M; Korbicz J;

Microscopic analysis of breast cancer images is the primary task in diagnosing cancer malignancy. Recent attempts to automate this task have employed deep learning models whose success has depended on large volumes of data, while acquiring annotated data in ...

Article GUID: 36758326


A "biphasic glycosyltransferase high-throughput screen" identifies novel anthraquinone glycosides in the diversification of phenolic natural products

Author(s): Mohideen FI; Kwan DH;

The sugar moieties of many glycosylated small molecule natural products are essential for their biological activity. Glycosyltransferases (GTs) are the enzymes responsible for installing these sugar moieties on a variety of biomolecules. Several GTs that ar ...

Article GUID: 36682498


Deep learning for collateral evaluation in ischemic stroke with imbalanced data

Author(s): Aktar M; Reyes J; Tampieri D; Rivaz H; Xiao Y; Kersten-Oertel M;

Purpose: Collateral evaluation is typically done using visual inspection of cerebral images and thus suffers from intra- and inter-rater variability. Large open databases of ischemic stroke patients are rare, limiting the use of deep learni ...

Article GUID: 36635594


Upconversion Luminescence through Cooperative and Energy-Transfer Mechanisms in Yb3+ -Metal-Organic Frameworks

Author(s): Xie Y; Sun G; Mandl GA; Maurizio SL; Chen J; Capobianco JA; Sun L;

Lanthanide-doped metal-organic frameworks (Ln-MOFs) have versatile luminescence properties, however it is challenging to achieve lanthanide-based upconversion luminescence in these materials. Here, 1,3,5-benzenetricarboxylic acid (BTC) and trivalent Yb3+ io ...

Article GUID: 36437239


LIST: A Newly Developed Laser-assisted Cell Bioprinting Technology

Author(s): Roversi K; Orimi HE; Erfanian M; Talbot S; Boutopoulos C;

Cell bioprinting technologies aim to fabricate tissue-like constructs by delivering biomaterials layer-by-layer. Bioprinted constructs can reduce the use of animals in drug development and hold promise for addressing the shortage of organs for transplants. ...

Article GUID: 36313198


Photoactivation and conformational gating for manganese binding and oxidation in bacterial reaction centers

Author(s): Samaei A; Deshmukh SS; Protheroe C; Nyéki S; Tremblay-Ethier RA; Kálmán L;

The influence of illumination history of native bacterial reaction centers (BRCs) on the ability of binding and photo-induced oxidation of manganous ions was investigated in the pH range between 8.0 and 9.4. Binding of manganous ions to a buried site requir ...

Article GUID: 36216075


Trust-Augmented Deep Reinforcement Learning for Federated Learning Client Selection

Author(s): Rjoub G; Wahab OA; Bentahar J; Cohen R; Bataineh AS;

In the context of distributed machine learning, the concept of federated learning (FL) has emerged as a solution to the privacy concerns that users have about sharing their own data with a third-party server. FL allows a group of users (often referred to as ...

Article GUID: 35875592


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