Keyword search (4,163 papers available)

"Ottenwaelder X" Authored Publications:

Title Authors PubMed ID
1 Overlap and Covalency in a κN-Arylnitrosyl Cu(II) Metalloradical Formed by Hydroxylamine Oxidative Binding MacKay A; Zsombor-Pindera J; Effaty F; Sheibany N; Gennarini F; Habibian M; Chen F; Askari MS; Brytskyi M; Kroeker S; Kennepohl P; Ottenwaelder X; 41524899
CHEMBIOCHEM
2 Mechanochemistry for Metal-Organic Frameworks and Covalent-Organic Frameworks (MOFs, COFs): Methods, Materials, and Mechanisms Marrett JM; Effaty F; Ottenwaelder X; Frišcic T; 40708349
CHEMBIOCHEM
3 Mechanochemical Synthesis of Boroxine-linked Covalent Organic Frameworks Hamzehpoor E; Effaty F; Borchers TH; Stein RS; Wahrhaftig-Lewis A; Ottenwaelder X; Frišcic T; Perepichka DF; 38970305
CHEMBIOCHEM
4 Cooperative Sensitization Upconversion in Solution Dispersions of Co-Crystal Assemblies of Mononuclear Yb3+ and Eu3+ Complexes Sun G; Xie Y; Wang Y; Mandl GA; Maurizio SL; Zhang H; Ottenwaelder X; Capobianco JA; Sun L; 37040148
CNSR
5 Resonant acoustic mixing (RAM) for efficient mechanoredox catalysis without grinding or impact media Effaty F; Gonnet L; Koenig SG; Nagapudi K; Ottenwaelder X; Frišcic T; 36546478
CHEMBIOCHEM
6 Intramolecular H-bond stabilization of a primary hydroxylamine in salen-type metal complexes Singh H; MacKay A; Sheibany N; Chen F; Mosser M; Rouet PÉ; Rousseau F; Askari MS; Ottenwaelder X; 34545379
CHEMBIOCHEM
7 Programmed Synthesis of Tetra-Aryl Thiophenes with Stepwise, Ester-Controlled Regioselectivity Messina C; Ottenwaelder X; Forgione P; 34506149
CHEMBIOCHEM
8 Five Nitrogen Oxidation States from Nitro to Amine: Stabilization and Reactivity of a Metastable Arylhydroxylamine Complex. Zsombor-Pindera J; Effaty F; Escomel L; Patrick B; Kennepohl P; Ottenwaelder X; 33124796
CHEMBIOCHEM
9 Tuning Inner-Sphere Electron Transfer in a Series of Copper/Nitrosoarene Adducts. Askari MS, Effaty F, Gennarini F, Orio M, Le Poul N, Ottenwaelder X 32073833
CHEMBIOCHEM
10 A bio-inspired synthesis of oxindoles by catalytic aerobic dual C-H functionalization of phenols. Huang Z, Askari MS, Esguerra KVN, Dai TY, Kwon O, Ottenwaelder X, Lumb JP 29861988
CHEMISTRY
11 Synthesis of Highly Functionalized Triarylbismuthines by Functional Group Manipulation and Use in Palladium- and Copper-Catalyzed Arylation Reactions. Hébert M, Petiot P, Benoit E, Dansereau J, Ahmad T, Le Roch A, Ottenwaelder X, Gagnon A 27231755
CHEMBIOCHEM
12 Supramolecular control of monooxygenase reactivity in a copper(ii) cryptate. Chaloner L, Khomutovskaya A, Thomas F, Ottenwaelder X 27328176
CHEMBIOCHEM

 

Title:Cooperative Sensitization Upconversion in Solution Dispersions of Co-Crystal Assemblies of Mononuclear Yb3+ and Eu3+ Complexes
Authors:Sun GXie YWang YMandl GAMaurizio SLZhang HOttenwaelder XCapobianco JASun L
Link:https://pubmed.ncbi.nlm.nih.gov/37040148/
DOI:10.1002/anie.202304591
Publication:Angewandte Chemie (International ed. in English)
Keywords:Co-CrystalCooperative Sensitization UpconversionDown-Shifting LuminescenceLanthanide ComplexMolecular Upconversion Luminescence
PMID:37040148 Category: Date Added:2023-05-04
Dept Affiliation: CNSR
1 School of Materials Science and Engineering, Shanghai University, Shanghai, 200444, China.
2 Department of Chemistry, College of Sciences, Shanghai University, Shanghai, 200444, China.
3 Department of Chemistry and Biochemistry and Centre for NanoScience Research, Concordia University, Montreal, QC H4B 1R6, Canada.
4 State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, China.

Description:

Lanthanide upconversion luminescence in nanoparticles has prompted continuous breakthroughs in information storage, temperature sensing, and biomedical applications, among others. Achieving upconversion luminescence at the molecular scale is still a critical challenge in modern chemistry. In this work, we explored the upconversion luminescence of solution dispersions of co-crystals composed of discrete mononuclear Yb(DBM)3 Bpy and Eu(DBM)3 Bpy complexes (DBM: dibenzoylmethane, Bpy: 2,2'-bipyridine). The 613 nm emission of Eu3+ was observed under excitation of Yb3+ at 980 nm. From the series of molecular assemblies studied, the most intense luminescence was obtained for a 1 : 1 molar ratio of Yb3+ : Eu3+ , resulting in a high quantum yield of 0.67 % at 2.1 W cm-2 . The structure and energy transfer mechanism of the assemblies were fully characterized. This is the first example of an Eu3+ -based upconverting system composed of two discrete mononuclear lanthanide complexes present as co-crystals in non-deuterated solution.





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