Keyword search (4,164 papers available)

"Chemistry" Keyword-tagged Publications:

Title Authors PubMed ID
1 Mechanochemistry for Metal-Organic Frameworks and Covalent-Organic Frameworks (MOFs, COFs): Methods, Materials, and Mechanisms Marrett JM; Effaty F; Ottenwaelder X; Frišcic T; 40708349
CHEMBIOCHEM
2 Sustainable Recovery of Critical Minerals from Wastes by Green Biosurfactants: A Review Deravian B; Mulligan CN; 40509347
ENCS
3 Comprehensive Analysis of Age- and Sex-Related Expression of the Chaperone Protein Sigma-1R in the Mouse Brain Tarmoun K; Lachance V; Le Corvec V; Bélanger SM; Beaucaire G; Kourrich S; 39335377
CSBN
4 Mechanochemical Synthesis of Boroxine-linked Covalent Organic Frameworks Hamzehpoor E; Effaty F; Borchers TH; Stein RS; Wahrhaftig-Lewis A; Ottenwaelder X; Frišcic T; Perepichka DF; 38970305
CHEMBIOCHEM
5 Molecular copper(I)-sensitized photoanodes for alcohol oxidation under ambient conditions Ricardo-Noordberg J; Kamal S; Majewski M; 38932662
CHEMBIOCHEM
6 Design, Synthesis, and Acid-Responsive Disassembly of Shell-Sheddable Block Copolymer Labeled with Benzaldehyde Acetal Junction Andrade-Gagnon B; Casillas-Popova SN; Jazani AM; Oh JK; 38499007
CHEMBIOCHEM
7 Using 13C enriched acetate in isotope labelling incubation experiments: a note of caution Leone F; Imfeld A; Mirzaei Y; Gélinas Y; 38097918
CHEMBIOCHEM
8 An electrochemical aptasensor for Δ9-tetrahydrocannabinol detection in saliva on a microfluidic platform Kékedy-Nagy L; Perry JM; Little SR; Llorens OY; Shih SCC; 36549107
BIOLOGY
9 Droplet digital microfluidic system for screening filamentous fungi based on enzymatic activity Samlali K; Alves CL; Jezernik M; Shih SCC; 36438986
BIOLOGY
10 On the Origin of Sugar Handedness: Facts, Hypotheses and Missing Links-A Review Martínez RF; Cuccia LA; Viedma C; Cintas P; 35796896
CHEMBIOCHEM
11 Diverse Applications of Biomass-Derived 5-Hydroxymethylfurfural and Derivatives as Renewable Starting Materials Chacón-Huete F; Messina C; Cigana B; Forgione P; 35652539
CHEMBIOCHEM
12 Electrochemical nutrient removal from natural wastewater sources and its impact on water quality Kékedy-Nagy L; English L; Anari Z; Abolhassani M; Pollet BG; Popp J; Greenlee LF; 34974342
CSFG
13 Self-Healable Reprocessable Triboelectric Nanogenerators Fabricated with Vitrimeric Poly(hindered Urea) Networks. Patel T, Kim MP, Park J, Lee TH, Nellepalli P, Noh SM, Jung HW, Ko H, Oh JK 32840992
CHEMBIOCHEM
14 Modular Construction of Porous Hydrogen-Bonded  Molecular Materials from Melams. Khadivjam T, Che-Quang H, Maris T, Ajoyan Z, Howarth A, Wuest JD 32115786
CONCORDIA
15 How does synchrony with host plant affect the performance of an outbreaking insect defoliator? Fuentealba A, Pureswaran D, Bauce É, Despland E 28756489
BIOLOGY
16 Reduction-Responsive Sheddable Carbon Nanotubes Dispersed in Aqueous Solution. An SY, Sun S, Oh JK 26890479
CNSR
17 Progress and Challenges in Ocean Metaproteomics and Proposed Best Practices for Data Sharing. Saito MA, Bertrand EM, Duffy ME, Gaylord DA, Held NA, Hervey WJ, Hettich RL, Jagtap PD, Janech MG, Kinkade DB, Leary DH, McIlvin MR, Moore EK, Morris RM, Neely BA, Nunn BL, Saunders JK, Shepherd AI, Symmonds NI, Walsh DA 30702898
BIOLOGY
18 Biomarkers, designs, and interpretations of resting-state fMRI in translational pharmacological research: A review of state-of-the-Art, challenges, and opportunities for studying brain chemistry. Khalili-Mahani N, Rombouts SA, van Osch MJ, Duff EP, Carbonell F, Nickerson LD, Becerra L, Dahan A, Evans AC, Soucy JP, Wise R, Zijdenbos AP, van Gerven JM 28145075
PERFORM

 

Title:Mechanochemical Synthesis of Boroxine-linked Covalent Organic Frameworks
Authors:Hamzehpoor EEffaty FBorchers THStein RSWahrhaftig-Lewis AOttenwaelder XFrišcic TPerepichka DF
Link:https://pubmed.ncbi.nlm.nih.gov/38970305/
DOI:10.1002/anie.202404539
Publication:Angewandte Chemie (International ed. in English)
Keywords:BoroxinesMechanochemistryPorous materialsResonant Acoustic Mixingcovalent organic frameworks
PMID:38970305 Category: Date Added:2024-07-06
Dept Affiliation: CHEMBIOCHEM
1 McGill University, Chemistry, CANADA.
2 Concordia University, Chemistry and Biochemistry, CANADA.
3 University of Birmingham, Chemistry, UNITED KINGDOM.
4 Bruker UK Ltd, Bruker UK Ltd, UNITED KINGDOM OF GREAT BRITAIN AND NORTHERN IRELAND.
5 McGill University, Department of Chemistry, 801 Sherbrooke Street West, H3A 0B8, Montreal, CANADA.

Description:

We report a rapid, room-temperature mechanochemical synthesis of 2- and 3-dimensional boroxine covalent organic frameworks (COFs), enabled by using trimethylboroxine as a dehydrating additive to overcome the hydrolytic sensitivity of boroxine-based COFs. The resulting COFs display high porosity and crystallinity, with COF-102 being the first example of a mechanochemically prepared 3D COF, exhibiting a surface area of ca. 2,500 m2 g-1. Mechanochemistry enabled a >20-fold reduction in solvent use and ~100-fold reduction in reaction time compared with solvothermal methods, providing target COFs quantitatively with no additional work-up besides vacuum drying. Real-time Raman spectroscopy permitted the first quantitative kinetic analysis of COF mechanosynthesis, while transferring the reaction design to Resonant Acoustic Mixing (RAM) enabled synthesis of multi-gram amounts of the target COFs (tested up to 10 g).





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