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"XAS" Keyword-tagged Publications:

Title Authors PubMed ID
1 Single-Atom Catalyst with Optimized Ni Content in a Flexible Zn-Air Battery Operated at a Wide Temperature Range Coello-Mauleón C; Ramos-Castillo CM; Arredondo-Espínola A; Álvarez-Contreras L; Guerra-Balcázar M; Chen N; Deng S; Arjona N; 41003649
ENCS

 

Title:Single-Atom Catalyst with Optimized Ni Content in a Flexible Zn-Air Battery Operated at a Wide Temperature Range
Authors:Coello-Mauleón CRamos-Castillo CMArredondo-Espínola AÁlvarez-Contreras LGuerra-Balcázar MChen NDeng SArjona N
Link:https://pubmed.ncbi.nlm.nih.gov/41003649/
DOI:10.1021/acsami.5c13455
Publication:ACS applied materials & interfaces
Keywords:Oxygen reduction reactionSingle-atom catalystXASZIF-8Zn-air battery
PMID:41003649 Category: Date Added:2025-09-26
Dept Affiliation: ENCS
1 Centro de Investigación y Desarrollo Tecnológico en Electroquímica S. C., Pedro Escobedo, Querétaro C. P. 76703, México.
2 Centro de Investigación en Materiales Avanzados S. C., Complejo Industrial Chihuahua, Chihuahua, C. P. 31136, México.
3 Facultad de Ingeniería, División de Investigación y Posgrado, Universidad Autónoma de Querétaro, Querétaro C. P. 76010, México.
4 Canadian Light Source, 44 Innovation Boulevard, Saskatoon, Saskatchewan S7N 2 V3, Canada.
5 Department of Chemical and Materials Engineering, Concordia University, Montreal, QC H3G 1M8, Canada.

Description:

Flexible and safe energy storage systems are critical for the advancement of wearable and portable electronics. Although lithium-ion batteries dominate the market, their reliance on flammable electrolytes and rigid structures limits their use in flexible applications. Herein, we report the development of a flexible Zn-air battery featuring a nitrogen-doped lamellar carbon cathode embedded with Ni single-atom catalytic sites. The battery demonstrated a high areal capacity of ~32 mA·h cm-2 and sustained stable operation over nearly 325 charge-discharge cycles. It also achieved a maximum discharge current density of 150 mA cm-2 under the polarization conditions. In the half-cell configuration, the optimized Ni-Nx catalyst exhibited a low overpotential of 1.45 V vs. RHE at 10 mA cm-2 for the oxygen evolution reaction, outperforming the benchmark IrO2 catalyst (1.49 V vs. RHE). The full cell maintained excellent electrochemical stability across a broad temperature range (5-60 °C) and retained its functionality under severe mechanical deformation, including bending, cutting, and puncturing. Postcycling SEM analysis revealed the formation of vertically aligned Zn nanostructures that effectively suppressed dendrite growth.





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