Keyword search (4,163 papers available)

"manganese" Keyword-tagged Publications:

Title Authors PubMed ID
1 Manganese-Based Spinel Cathodes: A Promising Frontier for Solid-State Lithium-Ion Batteries Dou Y; Zhou S; Dawkins JIG; Zaghib K; Amine K; Xu GL; Deng S; 41137442
ENCS
2 Transcriptomics identify the triggering of citrate export as the key event caused by manganese deficiency in Aspergillus niger Fekete E; Bíró V; Márton A; Bakondi-Kovács I; Sándor E; Kovács B; Geoffrion N; Tsang A; Kubicek CP; Karaffa L; 39377610
CSFG
3 Bioreactor as the root cause of the "manganese effect" during Aspergillus niger citric acid fermentations Fekete E; Bíró V; Márton A; Bakondi-Kovács I; Németh Z; Sándor E; Kovács B; Fábián I; Kubicek CP; Tsang A; Karaffa L; 35992333
CSFG
4 The effects of external Mn2+ concentration on hyphal morphology and citric acid production are mediated primarily by the NRAMP-family transporter DmtA in Aspergillus niger. Fejes B, Ouedraogo JP, Fekete E, Sándor E, Flipphi M, Soós Á, Molnár ÁP, Kovács B, Kubicek CP, Tsang A, Karaffa L 32000778
CSFG

 

Title:Manganese-Based Spinel Cathodes: A Promising Frontier for Solid-State Lithium-Ion Batteries
Authors:Dou YZhou SDawkins JIGZaghib KAmine KXu GLDeng S
Link:https://pubmed.ncbi.nlm.nih.gov/41137442/
DOI:10.1002/adma.202514126
Publication:Advanced materials (Deerfield Beach, Fla.)
Keywords:characterizationmanganesesolid‐state batteriessolid‐state electrolytesspinel cathode
PMID:41137442 Category: Date Added:2025-10-25
Dept Affiliation: ENCS
1 Department of Chemical and Materials Engineering, Concordia University, Montreal, Quebec, H3G 1M8, Canada.
2 Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, IL, 60439, USA.
3 Pritzker School of Molecular Engineering, The University of Chicago, 5801 South Ellis Ave, Chicago, Illinois, 60637, United States.

Description:

Recently, all-solid-state lithium-ion batteries (ASSLIBs), which exhibit improved safety and enhanced energy density compared to conventional commercialized lithium-ion batteries (LIBs), thereby have garnered extensive research interest. Among the promising cathode candidates, Mn-based spinel cathodes LiMn2O4 (LMO) and LiNi0.5Mn1.5O4 (LNMO), with the unique characteristics of low cost, structural stability, and 3D Li-ion diffusion channels, have demonstrated excellent performance in LIBs and presented great potential in ASSLIBs applications. However, several challenges, including structural degradations, poor interfacial contact, large interfacial resistance, and Mn-dissolution/diffusion during the electrochemical cycling, hinder their practical applications and commercialization in the ASSLIBs. Particularly, the high-voltage LNMO cathodes suffer from the challenge of electrochemical incompatibility with most of the solid-state electrolytes (SSEs). Herein, the spinel structure, the electrochemical behavior, and the structural degradation of the LMO/LNMO are explored. The characteristics and recent progress of the mitigating strategies to the challenges of various SSEs, including polymer-, oxide-, composite-, sulfide-, halide-, and LiPON-based SSEs, are introduced when paired with LMO/LNMO. Finally, the directions for future research to advance Mn-based spinel cathodes and fulfill the requirements of the next-generation ASSLIBs are also discussed.





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