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PubMed Publications| Keyword search (4,164 papers available) |  |
"organic framework" Keyword-tagged Publications:
| Title | Authors | PubMed ID | |
|---|---|---|---|
| 1 | Optimizing Mixtures of Metal-Organic Frameworks for Robust and Bespoke Passive Atmospheric Water Harvesting | Harriman C; Ke Q; Vlugt TJH; Howarth AJ; Simon CM; | 41427123 CHEMBIOCHEM |
| 2 | Mechanochemistry for Metal-Organic Frameworks and Covalent-Organic Frameworks (MOFs, COFs): Methods, Materials, and Mechanisms | Marrett JM; Effaty F; Ottenwaelder X; Frišcic T; | 40708349 CHEMBIOCHEM |
| 3 | Upconversion Lanthanide-Based 2D Metal-Organic Frameworks for Multimode Information Encryption | Chen J; Xie Y; Yang W; Sun R; Xing F; Mandl GA; Capobianco JA; Sun L; | 40557752 CNSR |
| 4 | Synthesis, Characterization and Photophysical Properties of a New Family of Rare-earth Cluster-based Metal-organic Frameworks | Bicalho HA; Copeman C; Barbosa HP; Donnarumma PR; Davis Z; Quezada-Novoa V; Velazquez-Garcia JJ; Liu N; Hemmer E; Howarth AJ; | 39105655 CHEMBIOCHEM |
| 5 | Mechanochemical Synthesis of Boroxine-linked Covalent Organic Frameworks | Hamzehpoor E; Effaty F; Borchers TH; Stein RS; Wahrhaftig-Lewis A; Ottenwaelder X; Frišcic T; Perepichka DF; | 38970305 CHEMBIOCHEM |
| 6 | The Effect of Linker-to-Metal Energy Transfer on the Photooxidation Performance of an Isostructural Series of Pyrene-Based Rare-Earth Metal-Organic Frameworks | Quezada-Novoa V; Titi HM; Villanueva FY; Wilson MWB; Howarth AJ; | 37116124 CHEMBIOCHEM |
| 7 | Upconversion Luminescence through Cooperative and Energy-Transfer Mechanisms in Yb3+ -Metal-Organic Frameworks | Xie Y; Sun G; Mandl GA; Maurizio SL; Chen J; Capobianco JA; Sun L; | 36437239 CNSR |
| 8 | A historical perspective on porphyrin-based metal-organic frameworks and their applications | Zhang X; Wasson MC; Shayan M; Berdichevsky EK; Ricardo-Noordberg J; Singh Z; Papazyan EK; Castro AJ; Marino P; Ajoyan Z; Chen Z; Islamoglu T; Howarth AJ; Liu Y; Majewski MB; Katz MJ; Mondloch JE; Farha OK; | 33678810 CNSR |
| Title: | Mechanochemical Synthesis of Boroxine-linked Covalent Organic Frameworks | ||||
| Authors: | Hamzehpoor E, Effaty F, Borchers TH, Stein RS, Wahrhaftig-Lewis A, Ottenwaelder X, Frišcic T, Perepichka DF | ||||
| Link: | https://pubmed.ncbi.nlm.nih.gov/38970305/ | ||||
| DOI: | 10.1002/anie.202404539 | ||||
| Publication: | Angewandte Chemie (International ed. in English) | ||||
| Keywords: | Boroxines; Mechanochemistry; Porous materials; Resonant Acoustic Mixing; covalent organic frameworks; | ||||
| PMID: | 38970305 | Category: | Date Added: | 2024-07-06 | |
| Dept Affiliation: |
CHEMBIOCHEM
1 McGill University, Chemistry, CANADA. 2 Concordia University, Chemistry and Biochemistry, CANADA. 3 University of Birmingham, Chemistry, UNITED KINGDOM. 4 Bruker UK Ltd, Bruker UK Ltd, UNITED KINGDOM OF GREAT BRITAIN AND NORTHERN IRELAND. 5 McGill University, Department of Chemistry, 801 Sherbrooke Street West, H3A 0B8, Montreal, CANADA. |
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Description: |
We report a rapid, room-temperature mechanochemical synthesis of 2- and 3-dimensional boroxine covalent organic frameworks (COFs), enabled by using trimethylboroxine as a dehydrating additive to overcome the hydrolytic sensitivity of boroxine-based COFs. The resulting COFs display high porosity and crystallinity, with COF-102 being the first example of a mechanochemically prepared 3D COF, exhibiting a surface area of ca. 2,500 m2 g-1. Mechanochemistry enabled a >20-fold reduction in solvent use and ~100-fold reduction in reaction time compared with solvothermal methods, providing target COFs quantitatively with no additional work-up besides vacuum drying. Real-time Raman spectroscopy permitted the first quantitative kinetic analysis of COF mechanosynthesis, while transferring the reaction design to Resonant Acoustic Mixing (RAM) enabled synthesis of multi-gram amounts of the target COFs (tested up to 10 g). |
