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PubMed Publications| Keyword search (4,164 papers available) |  |
"porous" Keyword-tagged Publications:
| Title | Authors | PubMed ID | |
|---|---|---|---|
| 1 | Mechanochemical Synthesis of Boroxine-linked Covalent Organic Frameworks | Hamzehpoor E; Effaty F; Borchers TH; Stein RS; Wahrhaftig-Lewis A; Ottenwaelder X; Frišcic T; Perepichka DF; | 38970305 CHEMBIOCHEM |
| 2 | Prolonged drying impedes the detachment of microplastics in unsaturated substrate: Role of flow regimes | Feng Q; Chen Z; Huang G; An C; Yang X; Wang Z; | 38340454 ENCS |
| 3 | Hydrophilic and underwater superoleophobic porous graphitic carbon nitride (g-C3N4) membranes with photo-Fenton self-cleaning ability for efficient oil/water separation | Yue R; Saifur Rahaman M; | 34749146 ENCS |
| 4 | Modular Construction of Porous Hydrogen-Bonded Molecular Materials from Melams. | Khadivjam T, Che-Quang H, Maris T, Ajoyan Z, Howarth A, Wuest JD | 32115786 CONCORDIA |
| 5 | Fabrication of Porous Gold Film Using Graphene Oxide as a Sacrificial Layer. | Alazzam A, Alamoodi N, Abutayeh M, Stiharu I, Nerguizian V | 31323903 ENCS |
| Title: | Mechanochemical Synthesis of Boroxine-linked Covalent Organic Frameworks | ||||
| Authors: | Hamzehpoor E, Effaty F, Borchers TH, Stein RS, Wahrhaftig-Lewis A, Ottenwaelder X, Frišcic T, Perepichka DF | ||||
| Link: | https://pubmed.ncbi.nlm.nih.gov/38970305/ | ||||
| DOI: | 10.1002/anie.202404539 | ||||
| Publication: | Angewandte Chemie (International ed. in English) | ||||
| Keywords: | Boroxines; Mechanochemistry; Porous materials; Resonant Acoustic Mixing; covalent organic frameworks; | ||||
| PMID: | 38970305 | Category: | Date Added: | 2024-07-06 | |
| Dept Affiliation: |
CHEMBIOCHEM
1 McGill University, Chemistry, CANADA. 2 Concordia University, Chemistry and Biochemistry, CANADA. 3 University of Birmingham, Chemistry, UNITED KINGDOM. 4 Bruker UK Ltd, Bruker UK Ltd, UNITED KINGDOM OF GREAT BRITAIN AND NORTHERN IRELAND. 5 McGill University, Department of Chemistry, 801 Sherbrooke Street West, H3A 0B8, Montreal, CANADA. |
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Description: |
We report a rapid, room-temperature mechanochemical synthesis of 2- and 3-dimensional boroxine covalent organic frameworks (COFs), enabled by using trimethylboroxine as a dehydrating additive to overcome the hydrolytic sensitivity of boroxine-based COFs. The resulting COFs display high porosity and crystallinity, with COF-102 being the first example of a mechanochemically prepared 3D COF, exhibiting a surface area of ca. 2,500 m2 g-1. Mechanochemistry enabled a >20-fold reduction in solvent use and ~100-fold reduction in reaction time compared with solvothermal methods, providing target COFs quantitatively with no additional work-up besides vacuum drying. Real-time Raman spectroscopy permitted the first quantitative kinetic analysis of COF mechanosynthesis, while transferring the reaction design to Resonant Acoustic Mixing (RAM) enabled synthesis of multi-gram amounts of the target COFs (tested up to 10 g). |
