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"spine" Keyword-tagged Publications:
| Title: | Manganese-Based Spinel Cathodes: A Promising Frontier for Solid-State Lithium-Ion Batteries | ||||
| Authors: | Dou Y, Zhou S, Dawkins JIG, Zaghib K, Amine K, Xu GL, Deng S | ||||
| Link: | https://pubmed.ncbi.nlm.nih.gov/41137442/ | ||||
| DOI: | 10.1002/adma.202514126 | ||||
| Publication: | Advanced materials (Deerfield Beach, Fla.) | ||||
| Keywords: | characterization; manganese; solid‐; state batteries; solid‐; state electrolytes; spinel cathode; | ||||
| PMID: | 41137442 | Category: | Date Added: | 2025-10-25 | |
| Dept Affiliation: |
ENCS
1 Department of Chemical and Materials Engineering, Concordia University, Montreal, Quebec, H3G 1M8, Canada. 2 Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, IL, 60439, USA. 3 Pritzker School of Molecular Engineering, The University of Chicago, 5801 South Ellis Ave, Chicago, Illinois, 60637, United States. |
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Description: |
Recently, all-solid-state lithium-ion batteries (ASSLIBs), which exhibit improved safety and enhanced energy density compared to conventional commercialized lithium-ion batteries (LIBs), thereby have garnered extensive research interest. Among the promising cathode candidates, Mn-based spinel cathodes LiMn2O4 (LMO) and LiNi0.5Mn1.5O4 (LNMO), with the unique characteristics of low cost, structural stability, and 3D Li-ion diffusion channels, have demonstrated excellent performance in LIBs and presented great potential in ASSLIBs applications. However, several challenges, including structural degradations, poor interfacial contact, large interfacial resistance, and Mn-dissolution/diffusion during the electrochemical cycling, hinder their practical applications and commercialization in the ASSLIBs. Particularly, the high-voltage LNMO cathodes suffer from the challenge of electrochemical incompatibility with most of the solid-state electrolytes (SSEs). Herein, the spinel structure, the electrochemical behavior, and the structural degradation of the LMO/LNMO are explored. The characteristics and recent progress of the mitigating strategies to the challenges of various SSEs, including polymer-, oxide-, composite-, sulfide-, halide-, and LiPON-based SSEs, are introduced when paired with LMO/LNMO. Finally, the directions for future research to advance Mn-based spinel cathodes and fulfill the requirements of the next-generation ASSLIBs are also discussed. |



