BookR: School of Health Core Facilities Booking
PubMed Publications| Keyword search (4,164 papers available) |  |
"tin(IV)" Keyword-tagged Publications:
| Title | Authors | PubMed ID | |
|---|---|---|---|
| 1 | Crystal structure and Hirshfeld surface analysis of tri-chlorido-(1,10-phenanthroline-κ2 N,N')phenyltin(IV) | Benlatreche T; Bensegueni MA; Dénès G; Golhen S; Merazig H; | 39372187 CHEMBIOCHEM |
| Title: | Crystal structure and Hirshfeld surface analysis of tri-chlorido-(1,10-phenanthroline-κ2 N,N')phenyltin(IV) | ||||
| Authors: | Benlatreche T, Bensegueni MA, Dénès G, Golhen S, Merazig H | ||||
| Link: | https://pubmed.ncbi.nlm.nih.gov/39372187/ | ||||
| DOI: | 10.1107/S2056989024009150 | ||||
| Publication: | Acta crystallographica. Section E, Crystallographic communications | ||||
| Keywords: | C-H⋯; Cl hydrogen bond; Hirshfeld surface analysis; crystal structure; phenanthroline; tin(IV); | ||||
| PMID: | 39372187 | Category: | Date Added: | 2024-10-07 | |
| Dept Affiliation: |
CHEMBIOCHEM
1 Environmental and Structural Molecular Chemistry Research Unit URCHEMS Faculty of Exact Sciences University of Constantine 1-Mentouri Brothers 25000 Algeria. 2 National Higher School for Hydraulics, Abdellah Arbaoui, Blida, Algeria. 3 Laboratory of Solid State Chemistry and Mössbauer Spectroscopy, Chemistry and Biochemistry Department, Concordia University, Montreal, Canada. 4 CNRS, Rennes Institute of Chemical Sciences - UMR 6226, University of Rennes, France. |
||||
Description: |
The title compound, [Sn(C6H5)Cl3(C12H8N2)], which was obtained by the reaction between 1,10-phenanthroline and phenyl-tin trichloride in methanol, exhibits intra-molecular hydrogen-bonding inter-actions involving the chlorine and hydrogen atoms. Crystal cohesion is ensured by inter-molecular C-H?Cl hydrogen bonds, as well as Y-X?p and p-stacking inter-actions involving three different aromatic rings with centroid-centroid distances of 3.6605 (13), 3.9327 (14) and 3.6938 (12) Å]. Hirshfeld surface analysis and the associated two-dimensional fingerprint plots reveal significant contributions from H?H (30.7%), Cl?H/H?Cl (32.4%), and C?H/H?C (24.0%) contacts to the crystal packing while the C?C (6.2%), C?Cl/Cl?C (4.1%), and N?H/H?N (1.7%) inter-actions make smaller contributions. |
