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Electrochemical efficacy of a carboxylated multiwalled carbon nanotube filter for the removal of ibuprofen from aqueous solutions under acidic conditions.

Author(s): Bakr AR, Rahaman MS

Chemosphere. 2016 Jun;153:508-20 Authors: Bakr AR, Rahaman MS

Article GUID: 27035389
Crossflow electrochemical filtration for elimination of ibuprofen and bisphenol a from pure and competing electrolytic solution conditions.

Author(s): Bakr AR, Rahaman MS

J Hazard Mater. 2019 Mar 05;365:615-621 Authors: Bakr AR, Rahaman MS

Article GUID: 30471576
Title:Electrochemical efficacy of a carboxylated multiwalled carbon nanotube filter for the removal of ibuprofen from aqueous solutions under acidic conditions.
Authors:Bakr AR,  Rahaman MS
Link:https://www.ncbi.nlm.nih.gov/pubmed/27035389?dopt=Abstract
DOI:10.1016/j.chemosphere.2016.03.078
Category:Chemosphere
PMID:27035389
Dept Affiliation: MASSSPEC
1 Department of Building, Civil and Environmental Engineering, Concordia University, Montreal, Quebec, H3G 1M8, Canada.
2 Department of Building, Civil and Environmental Engineering, Concordia University, Montreal, Quebec, H3G 1M8, Canada. Electronic address: saifur.rahaman@concordia.ca.

Description:

Electrochemical efficacy of a carboxylated multiwalled carbon nanotube filter for the removal of ibuprofen from aqueous solutions under acidic conditions.

Chemosphere. 2016 Jun;153:508-20

Authors: Bakr AR, Rahaman MS

Abstract

This study provides insight into the efficiency of a functionalized multiwalled carbon nanotube filter for the removal of an anti-inflammatory drug, ibuprofen, through conventional filtration and electrochemical filtration processes. A comparison was made between carboxylated multiwalled carbon nanotubes (MWNTs-COOH) and pristine multiwalled carbon nanotubes (MWNTs) in order to emphasize the enhanced performance of MWNTs-COOH for the removal of ibuprofen using an electrochemical filtration process under acidic conditions. Ibuprofen-removal trials were evaluated based on absorbance values obtained using a UV/Vis spectrophotometer, and possible degradation products were identified using liquid chromatography mass spectrometry (LC-MS). The results exhibited near complete removal of ibuprofen by MWNTs-COOH at lower applied potentials (2 V), at lower flow rates, and under acidic conditions, which can be attributed to the generation of superoxides and their active participation in simultaneous degradation of ibuprofen, and its by-products, under these conditions. At higher applied potential (3 V), the possible participation of both bulk indirect oxidation reactions, and direct electron transfer were hypothesized for the removal behavior over time (breakthrough). At 3 V under acidic conditions, near 100% removal of the target molecule was achieved and was attributed to the enhanced generation of electroactive species toward bulk chemical reactions and a possible contribution from direct electron transfer under these conditions. The degradation by-products of ibuprofen were effectively removed by allowing longer residence time during the filtration process. Moreover, the effect of temperature was studied, yet showed a non-significant effect on the overall removal process.

PMID: 27035389 [PubMed - indexed for MEDLINE]