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Synthesis, crystal structure and Hirshfeld surface of bis-(2-amino-pyridinium) hexa-chlorido-stannate(IV).

Author(s): Ghallab R, Boutebdja M, Dénès G, Merazig H

In the title mol-ecular salt, (C5H7N2)2[SnCl6], the cation is protonated at the pyridine N atom and the complete dianion is generated by a crystallographic centre of symmetry. In the crystal, N-H?Cl hydrogen bonds link the components into a three-dimensiona...

Article GUID: 32844014
Title:Synthesis, crystal structure and Hirshfeld surface of bis-(2-amino-pyridinium) hexa-chlorido-stannate(IV).
Authors:Ghallab R,  Boutebdja M,  Dénès G,  Merazig H
Link:https://www.ncbi.nlm.nih.gov/pubmed/32844014
DOI:10.1107/S205698902000941X
Category:Acta Crystallogr E Crystallogr Commun
PMID:32844014
Dept Affiliation: CHEMBIOCHEM
1 Environmental Molecular, and Structural Chemistry Research Unit, University of, Constantine-1, 25000, Constantine, Algeria.
2 Laboratory of Solid State Chemistry and Mossbauer Spectroscopy, Departement of, Chemistry and Biochemistry, Concordia University, 7141 Sherbrooke St. West, Montreal, H4B 1R6, QC, Canada.

Description:

Synthesis, crystal structure and Hirshfeld surface of bis-(2-amino-pyridinium) hexa-chlorido-stannate(IV).

Acta Crystallogr E Crystallogr Commun. 2020 Aug 01; 76(Pt 8):1279-1283

Authors: Ghallab R, Boutebdja M, Dénès G, Merazig H

Abstract

In the title mol-ecular salt, (C5H7N2)2[SnCl6], the cation is protonated at the pyridine N atom and the complete dianion is generated by a crystallographic centre of symmetry. In the crystal, N-H?Cl hydrogen bonds link the components into a three-dimensional network built up from the stacking of alternate cationic and anionic layers. The nature of the inter-molecular inter-actions has been analysed in terms of the Hirshfeld surfaces of the cations and the anions. The thermal behaviour and the Raman spectrum of the title compound are reported.

PMID: 32844014 [PubMed]