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Tuning of Morphology and Stability of Gold Nanostars Through pH Adjustment.

Author(s): Kumar R, Badilescu S, Packirisamy M

J Nanosci Nanotechnol. 2019 Aug 01;19(8):4617-4622 Authors: Kumar R, Badilescu S, Packirisamy M

Article GUID: 30913757
Directing the Viedma ripening of ethylenediammonium sulfate using "Tailor-made" chiral additives.

Author(s): Nguyen TP, Cheung PS, Werber L, Gagnon J, Sivakumar R, Lennox C, Sossin A, Mastai Y, Cuccia LA

Chem Commun (Camb). 2016 Oct 18;52(85):12626-12629 Authors: Nguyen TP, Cheung PS, Werber L, Gagnon J, Sivakumar R, Lennox C, Sossin A, Mastai Y, Cuccia LA

Article GUID: 27722259
Title:Directing the Viedma ripening of ethylenediammonium sulfate using "Tailor-made" chiral additives.
Authors:Nguyen TP,  Cheung PS,  Werber L,  Gagnon J,  Sivakumar R,  Lennox C,  Sossin A,  Mastai Y,  Cuccia LA
Link:https://www.ncbi.nlm.nih.gov/pubmed/27722259?dopt=Abstract
Category:Chem Commun (Camb)
PMID:27722259
Dept Affiliation: CHEMBIOCHEM
1 Department of Chemistry & Biochemistry, Concordia University, 7141 Sherbrooke Street West, Montréal, Québec H4B 1R6, Canada. Louis.Cuccia@concordia.ca.
2 Bar-Ilan University, Department of Chemistry, Ramat Gan, Israel. Yitzhak.Mastai@biu.ac.il.

Description:

Directing the Viedma ripening of ethylenediammonium sulfate using "Tailor-made" chiral additives.

Chem Commun (Camb). 2016 Oct 18;52(85):12626-12629

Authors: Nguyen TP, Cheung PS, Werber L, Gagnon J, Sivakumar R, Lennox C, Sossin A, Mastai Y, Cuccia LA

Abstract

Both enantiomers of trans-cyclohexane-1,2-diammonium sulfate and trans-1,2-diphenylethylenediammonium sulfate were used as "tailor-made" additives to direct the mirror-symmetry breaking in the attrition-enhanced deracemization (i.e. Viedma ripening) of conglomerate crystals of ethylenediammonium sulfate (EDS). Isothermal titration calorimetry (ITC) shows chiral recognition of (1R,2R)- and (1S,2S)-1,2-diphenylethylenediamine to EDS crystals where the enthalpy of adsorption of the (1R,2R)-isomer on l-EDS crystals is higher in comparison to that on d-EDS crystals. These results are consistent with a "rule of reversal" mechanism driving the chiral outcome of the Viedma ripening of EDS.

PMID: 27722259 [PubMed]