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Fluorinated Sterically Bulky Mononuclear and Binuclear 2-Iminopyridylnickel Halides for Ethylene Polymerization: Effects of Ligand Frameworks and Remote Substituents

Author(s): Zhang Q; Lin W; Liu T; Ye Z; Liang T; Sun WH;

In the present work, four new mono(imino)pyridine ligands, 2-((2,4-bis(bis(4-R-phenyl)methyl)-6-fluorophenylimino)methyl)pyridine (R = H, L1; R = OCH<sub>3</sub>, L2; R = F, L3) and 2-((2-(bis(4-fluorophenyl)methyl)-4-((3-(bis(4-fluorophenyl)methyl)-4-amine-5-fluoro-phenyl)(phenyl)methyl)-6-fluorophenylimino)methyl)pyridine (L4), have been des ...

Article GUID: 34778687


Human Activity Recognition: A Comparative Study to Assess the Contribution Level of Accelerometer, ECG, and PPG Signals

Author(s): Afzali Arani MS; Costa DE; Shihab E;

Inertial sensors are widely used in the field of human activity recognition (HAR), since this source of information is the most informative time series among non-visual datasets. HAR researchers are actively exploring other approaches and different sources of signals to improve the performance of HAR systems. In this study, we investigate the impact of co ...

Article GUID: 34770303


Maturation of temporal saccade prediction from childhood to adulthood: predictive saccades, reduced pupil size and blink synchronization

Author(s): Calancie OG; Brien DC; Huang J; Coe BC; Booij L; Khalid-Khan S; Munoz DP;

When presented with a periodic stimulus, humans spontaneously adjust their movements from reacting to predicting the timing of its arrival, but little is known about how this sensorimotor adaptation changes across development. To investigate this, we analyzed saccade behavior in 114 healthy humans (ages 6-24 years) performing the visual metronome task, wh ...

Article GUID: 34759032


In Vitro Reconstitution of the dTDP-l-Daunosamine Biosynthetic Pathway Provides Insights into Anthracycline Glycosylation

Author(s): Mohideen FI; Nguyen LH; Richard JD; Ouadhi S; Kwan DH;

Many small molecule natural products are decorated with sugar moieties that are essential for their biological activity. A considerable number of natural product glycosides and their derivatives are clinically important therapeutics. Anthracyclines like daunorubicin and doxorubicin are examples of valuable glycosylated natural products used in medicine as ...

Article GUID: 34751552


Engineering Yeast for De Novo Synthesis of the Insect Repellent Nepetalactone

Author(s): Davies ME; Tsyplenkov D; Martin VJJ;

While nepetalactone, the active ingredient in catnip, is a potent insect repellent, its low in planta accumulation limits its commercial viability as an alternative repellent. Here we describe for the first time de novo nepetalactone synthesis in Saccharomyces cerevisiae, enabling sustainable and scalable production. Nepetalactone production required intr ...

Article GUID: 34748704


Hydrophilic and underwater superoleophobic porous graphitic carbon nitride (g-C3N4) membranes with photo-Fenton self-cleaning ability for efficient oil/water separation

Author(s): Yue R; Saifur Rahaman M;

Due to the great fouling resistance property, (super)hydrophilic/underwater superoleophobic membranes are prevalent candidates for oil-polluted wastewater treatment. Even so, membrane fouling inevitably occurs during long-term operation. Therefore, it is of great significance to construct anti-fouling membranes with robust flux recovery. Herein, a polyvin ...

Article GUID: 34749146


Indeterminate and Enriched Propositions in Context Linger: Evidence From an Eye-Tracking False Memory Paradigm

Author(s): Antal C; de Almeida RG;

A sentence such as We finished the paper is indeterminate with regards to what we finished doing with the paper. Indeterminate sentences constitute a test case for two major issues regarding language comprehension: (1) how we compose sentence meaning; and (2) what is retained in memory about what we read in context over time. In an eye-tracking experiment ...

Article GUID: 34744914


Exploratory decisions of Trinidadian guppies when uncertain about predation risk

Author(s): Crane AL; Demers EE; Feyten LEA; Ramnarine IW; Brown GE;

Animals can reduce their uncertainty of predation risk by gathering new information via exploration behaviour. However, a decision to explore may also be costly due to increased predator exposure. Here, we found contextual effects of predation risk on the exploratory activity of Trinidadian guppies Poecilia reticulata in a novel environment. First, guppie ...

Article GUID: 34741669


The role of context on responding to an alcohol-predictive cue in female and male rats

Author(s): Segal D; Valyear MD; Chaudhri N;

In male rats, physical contexts that are associated with alcohol can amplify responding to a discrete, alcohol-predictive conditioned stimulus (CS), and amplify prime-induced reinstatement. Here, we examined these effects as a function of biological sex. Male and female Long-Evans rats were acclimated to drinking ethanol (15% v/v) in their home cages. Nex ...

Article GUID: 34742865


Intuitive eating and its association with psychosocial health in adults: A cross-sectional study in a representative Canadian sample

Author(s): Gödde JU; Yuan TY; Kakinami L; Cohen TR;

Intuitive eating has been proposed as a weight-inclusive, effective, and sustainable approach to eating that benefits psychosocial health compared to traditional restrictive dieting. This cross-sectional study examined the associations of intuitive eating with psychosocial health indicators and demographic characteristics in a representative Canadian samp ...

Article GUID: 34740711


An altered balance of integrated and segregated brain activity is a marker of cognitive deficits following sleep deprivation

Author(s): Cross NE; Pomares FB; Nguyen A; Perrault AA; Jegou A; Uji M; Lee K; Razavipour F; Ali OBK; Aydin U; Benali H; Grova C; Dang-Vu TT;

Sleep deprivation (SD) leads to impairments in cognitive function. Here, we tested the hypothesis that cognitive changes in the sleep-deprived brain can be explained by information processing within and between large-scale cortical networks. We acquired functional magnetic resonance imaging (fMRI ...

Article GUID: 34735431


Experimental relativistic zero-knowledge proofs

Author(s): Alikhani P; Brunner N; Crépeau C; Designolle S; Houlmann R; Shi W; Yang N; Zbinden H;

Protecting secrets is a key challenge in our contemporary information-based era. In common situations, however, revealing secrets appears unavoidable; for instance, when identifying oneself in a bank to retrieve money. In turn, this may have highly undesirable consequences in the unlikely, yet not unrealistic, case where the bank's security gets compr ...

Article GUID: 34732869


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