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Bulk Free Radical Terpolymerization of Butyl Acrylate, 2-Methylene-1,3-Dioxepane and Vinyl Acetate: Terpolymer Reactivity Ratio Estimation

Author(s): Movafagh M; Meek KM; Scott AJ; Penlidis A; Dubé MA;

This investigation introduces the first estimation of ternary reactivity ratios for a butyl acrylate (BA), 2-methylene-1,3-dioxepane (MDO), and vinyl acetate (VAc) system at 50 °C, with an aim to develop biodegradable pressure-sensitive adhesives (PSAs). In this study, we applied the error-in-variables model (EVM) to estimate reactivity ratios. The ternar ...

Article GUID: 38794524


Investigation of Macroscopic Mechanical Behavior of Magnetorheological Elastomers under Shear Deformation Using Microscale Representative Volume Element Approach

Author(s): Abdollahi I; Sedaghati R;

Magnetorheological elastomers (MREs) are a class of smart materials with rubber-like qualities, demonstrating revertible magnetic field-dependent viscoelastic properties, which makes them an ideal candidate for development of the next generation of adaptive vibration absorbers. This research study aims at the development of a finite element model using mi ...

Article GUID: 38794567


A decade of progress: bringing mixed reality image-guided surgery systems in the operating room

Author(s): Asadi Z; Asadi M; Kazemipour N; Léger É; Kersten-Oertel M;

Advancements in mixed reality (MR) have led to innovative approaches in image-guided surgery (IGS). In this paper, we provide a comprehensive analysis of the current state of MR in image-guided procedures across various surgical domains. Using the Data Visualization View (DVV) Taxonomy, we analyze the progress made since a 2013 literature review paper on ...

Article GUID: 38794834


Natural history of TANGO2 deficiency disorder: Baseline assessment of 73 patients

Author(s): Miyake CY; Lay EJ; Soler-Alfonso C; Glinton KE; Houck KM; Tosur M; Moran NE; Stephens SB; Scaglia F; Howard TS; Kim JJ; Pham TD; Valdes SO; Li N; Murali CN; Zhang L; Kava M; Yim D; Beach C; Webster G; Liberman L; Janson CM; Kannankeril P ...

Purpose: TANGO2 deficiency disorder (TDD), an autosomal recessive disease first reported in 2016, is characterized by neurodevelopmental delay, seizures, intermittent ataxia, hypothyroidism, and life-threatening metabolic and cardiac crises. The purpose of this study was to defin ...

Article GUID: 36473599


Language Exposure and Brain Myelination in Early Development

Author(s): Fibla L; Forbes SH; McCarthy J; Mee K; Magnotta V; Deoni S; Cameron D; Spencer JP;

The language environment to which children are exposed has an impact on later language abilities as well as on brain development; however, it is unclear how early such impacts emerge. This study investigates the effects of children's early language environment and socioeconomic status (SES) on brain structure in infancy at 6 and 30 months of age (both ...

Article GUID: 37188518


Measuring prion propagation in single bacteria elucidates mechanism of loss

Author(s): Jager K; Orozco-Hidalgo MT; Springstein BL; Joly-Smith E; Papazotos F; McDonough E; Fleming E; McCallum G; Hilfinger A; Hochschild A; Potvin-Trottier L;

Prions are self-propagating protein aggregates formed by specific proteins that can adopt alternative folds. Prions were discovered as the cause of the fatal transmissible spongiform encephalopathies in mammals, but prions can also constitute non-toxic protein-based elements of inheritance in fun ...

Article GUID: 36712035


Sibling-directed internal state language, perspective taking, and affective behavior

Author(s): Howe N;

This study examined relations among preschoolers' sibling-directed internal state language, perspective-taking abilities, and sibling-directed affective behaviors in 32 sibling dyads (aged 14 months and 3-4 years) during naturalistic home observations. Preschooler references about internal states (emotions, wants, abilities) were significantly more li ...

Article GUID: 1786731


"All the sheeps are dead. He murdered them": sibling pretense, negotiation, internal state language, and relationship quality

Author(s): Howe N; Petrakos H; Rinaldi CM;

Pretend play enactment, negotiation, internal state language, and sibling relationship quality were examined in 40 kindergarten-aged children with either an older (M age = 7.10 years) or younger (M age = 3.6 years) sibling. Dyads were identified as engaging in frequent (n = 20) or infrequent (n = 20) pretend play. Results indicated that frequent pretend p ...

Article GUID: 9499566


"No! The lambs can stay out because they got cozies": constructive and destructive sibling conflict, pretend play, and social understanding

Author(s): Howe N; Rinaldi CM; Jennings M; Petrakos H;

Associations among constructive and destructive sibling conflict, pretend play, internal state language, and sibling relationship quality were investigated in 40 middle-class dyads with a kindergarten-age child (M age = 5.7 years). In 20 dyads the sibling was older (M age = 7.1 years) and in 20 dyads the sibling was younger (M age = 3.6 years). Dyads were ...

Article GUID: 12361312


"This is a bad dog, you know...": constructing shared meanings during sibling pretend play

Author(s): Howe N; Petrakos H; Rinaldi CM; LeFebvre R;

The construction of shared meanings in play, pretense enactment, internal state language, and sibling relationship quality were investigated in 40 kindergarteners with an older (M age = 7.10 years) or younger (M age = 3.6 years) sibling. Dyadic strategies to construct shared meanings (e.g., extensions, building on) were positively associated with frequenc ...

Article GUID: 16026496


Playmates and teachers: reciprocal and complementary interactions between siblings

Author(s): Howe N; Recchia H;

Associations between siblings' reciprocal (i.e., play) and complementary (i.e., teaching) interactions in 70 sibling dyads (1st-born siblings' mean age=81.6 months, range=59-119 months; 2nd-born siblings' mean age = 56.1 months, range = 5-79 months) were examined. Dyads participated in 2 sessions (play, teaching) and completed a sibling relati ...

Article GUID: 16402864


What do second language listeners know about spoken words? Effects of experience and attention in spoken word processing

Author(s): Pavel Trofimovich

With a goal of investigating psycholinguistic bases of spoken word processing in a second language (L2), this study examined L2 learners' sensitivity to phonological information in spoken L2 words as a function of their L2 experience and attentional demands of a learning task. Fifty-two Chinese learners of English who differed in amount of L2 experien ...

Article GUID: 18330706


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