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Effect of Fe2+ ions on gypsum precipitation during bulk crystallization of reverse osmosis concentrates.

Author(s): Melliti E, Touati K, Van der Bruggen B, Elfil H

In reverse osmosis desalination, the concentrate is a saline solution that may become supersaturated. Heterogeneous nucleation of salts occurs at the membrane surface, resulting in the buildup of inorganic deposits on the membrane. The inorganic nucleation ...

Article GUID: 32814139

Effects of chronic exposure to selenomethionine on social learning outcomes in zebrafish (Danio rerio): serotonergic dysregulation and oxidative stress in the brain.

Author(s): Attaran A, Salahinejad A, Naderi M, Crane AL, Niyogi S, Chivers DP

Chemosphere. 2020 Jan 11;247:125898 Authors: Attaran A, Salahinejad A, Naderi M, Crane AL, Niyogi S, Chivers DP

Article GUID: 31972490

Exploring the use of ceramic disk filter coated with Ag/ZnO nanocomposites as an innovative approach for removing Escherichia coli from household drinking water.

Author(s): Huang J, Huang G, An C, Xin X, Chen X, Zhao Y, Feng R, Xiong W

Chemosphere. 2019 Dec 06;245:125545 Authors: Huang J, Huang G, An C, Xin X, Chen X, Zhao Y, Feng R, Xiong W

Article GUID: 31864067

A biophysiological perspective on enhanced nitrate removal from decentralized domestic sewage using gravitational-flow multi-soil-layering systems.

Author(s): Song P, Huang G, Hong Y, An C, Xin X, Zhang P

Chemosphere. 2019 Sep 14;240:124868 Authors: Song P, Huang G, Hong Y, An C, Xin X, Zhang P

Article GUID: 31542583

Electrochemical efficacy of a carboxylated multiwalled carbon nanotube filter for the removal of ibuprofen from aqueous solutions under acidic conditions.

Author(s): Bakr AR, Rahaman MS

Chemosphere. 2016 Jun;153:508-20 Authors: Bakr AR, Rahaman MS

Article GUID: 27035389

Electro-demulsification of water-in-oil suspensions enhanced with implementing various additives.

Author(s): Taslimi Taleghani S, Fellah Jahromi A, Elektorowicz M

Chemosphere. 2019 May 20;233:157-163 Authors: Taslimi Taleghani S, Fellah Jahromi A, Elektorowicz M

Article GUID: 31173953

Hierarchical magnetic petal-like Fe3O4-ZnO@g-C3N4 for removal of sulfamethoxazole, suppression of photocorrosion, by-products identification and toxicity assessment

Author(s): Mirzaei A; Chen Z; Haghighat F; Yerushalmi L;

Herein, a petal-like photocatalyst, Fe3O4-ZnO@g-C3N4 (FZG) with different g-C3N4 to ZnO ratios was synthesized with hierarchical structure. The FZG1 photocatalyst, having the weight ratio of 1:1 for the initial urea and Fe3O4-ZnO (Fe-ZnO), presented the hig...

Article GUID: 29705637

Hydrothermal/solvothermal synthesis and treatment of TiO2 for photocatalytic degradation of air pollutants: Preparation, characterization, properties, and performance.

Author(s): Mamaghani AH, Haghighat F, Lee CS

Chemosphere. 2019 Mar;219:804-825 Authors: Mamaghani AH, Haghighat F, Lee CS

Article GUID: 30572234

Wastewater treatment in amine-based carbon capture.

Author(s): Dong C, Huang G, Cheng G, An C, Yao Y, Chen X, Chen J

Chemosphere. 2019 May;222:742-756 Authors: Dong C, Huang G, Cheng G, An C, Yao Y, Chen X, Chen J

Article GUID: 30738317


Title:Hierarchical magnetic petal-like Fe3O4-ZnO@g-C3N4 for removal of sulfamethoxazole, suppression of photocorrosion, by-products identification and toxicity assessment
Authors:Mirzaei AChen ZHaghighat FYerushalmi L
Link:https://pubmed.ncbi.nlm.nih.gov/29705637/
DOI:10.1016/j.chemosphere.2018.04.102
Category:Chemosphere
PMID:29705637
Dept Affiliation: ENCS
1 Department of Building, Civil and Environmental Engineering (BCEE), Faculty of Engineering & Computer Sciences, Concordia University, Montreal, Quebec, Canada.
2 Department of Building, Civil and Environmental Engineering (BCEE), Faculty of Engineering & Computer Sciences, Concordia University, Montreal, Quebec, Canada. Electronic address: zhichen@alcor.concordia.ca.

Description:

Herein, a petal-like photocatalyst, Fe3O4-ZnO@g-C3N4 (FZG) with different g-C3N4 to ZnO ratios was synthesized with hierarchical structure. The FZG1 photocatalyst, having the weight ratio of 1:1 for the initial urea and Fe3O4-ZnO (Fe-ZnO), presented the highest sulfamethoxazole (SMX) degradation rate of 0.0351 (min-1), which was 2.6 times higher than that of pristine ZnO. Besides the facile separation, the performance of photocatalyst was improved due to the function of iron oxide as an electron acceptor that reduced the electron/hole recombination rate. The coating of g-C3N4 on the Fe-ZnO surface not only acted as a protective layer for ZnO against photocorrosion, but it also enhanced the photocatalytic activity of the catalyst for SMX degradation through the heterojunction mechanism. By using the FZG1 photocatalyst, 95% SMX removal was obtained after 90 min reaction, while 47% COD and 30% TOC removal were achieved after 60 min treatment under a low energy-consuming UV lamp (10 W). Moreover, a substantial reduction in the solution toxicity was shown after the treatment, as compared with the SMX solution before treatment. The LC-HR-MS/MS analysis results showed that the concentration of most detected by-products produced after 90 min reaction by FZG1 was considerably lower than those obtained using other synthesized photocatalysts. By performing radical scavenging experiments, OH° radical was found to be the major reactive species. The FZG1 photocatalyst also displayed excellent reusability in five cycles and the leaching of zinc and iron ions was reduced by 54% and ~100%, respectively, after coating Fe-ZnO with g-C3N4.