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Author(s): Huang TS, Anzellotti D, Dedaldechamp F, Ibrahim RK
Plant Physiol. 2004 Apr;134(4):1366-76 Authors: Huang TS, Anzellotti D, Dedaldechamp F, Ibrahim RK
Article GUID: 15084728
Author(s): Memarian R, Ramamurthy AS
J Environ Sci Health A Tox Hazard Subst Environ Eng. 2012;47(10):1486-90 Authors: Memarian R, Ramamurthy AS
Article GUID: 22571537
Author(s): Grenier V, Huppé G, Lamarche M, Mireault P
J Anal Toxicol. 2012 Sep;36(7):523-8 Authors: Grenier V, Huppé G, Lamarche M, Mireault P
Article GUID: 22722059
Author(s): Blazy V, de Guardia A, Benoist JC, Daumoin M, Lemasle M, Wolbert D, Barrington S
Waste Manag. 2014 Jul;34(7):1125-38 Authors: Blazy V, de Guardia A, Benoist JC, Daumoin M, Lemasle M, Wolbert D, Barrington S
Article GUID: 24768513
Author(s): Deeds DA; Ghoshdastidar A; Raofie F; Guérette ÉA; Tessier A; Ariya PA;
Measurement of oxidized mercury, Hg(II), in the atmosphere poses a significant analytical challenge as Hg(II) is present at ultra-trace concentrations (picograms per cubic meter air). Current technologies are sufficiently sensitive to measure the total Hg p...
Article GUID: 25837315
Author(s): Beach A, Richard VR, Bourque S, Boukh-Viner T, Kyryakov P, Gomez-Perez A, Arlia-Ciommo A, Feldman R, Leonov A, Piano A, Svistkova V, Titorenko VI
Cell Cycle. 2015;14(11):1643-56 Authors: Beach A, Richard VR, Bourque S, Boukh-Viner T, Kyryakov P, Gomez-Perez A, Arlia-Ciommo A, Feldman R, Leonov A, Piano A, Svistkova V, Titorenko VI
Article GUID: 25839782
Author(s): Bakr AR, Rahaman MS
Chemosphere. 2016 Jun;153:508-20 Authors: Bakr AR, Rahaman MS
Article GUID: 27035389
Author(s): Joshua Heinemann
Biological assays often require expensive reagents and tedious manipulations. These shortcomings can be overcome using digitally operated microfluidic devices that require reduced sample volumes to automate assays. One particular challenge is integrating bi...
Article GUID: 27957569
Author(s): Minogianis EA; Shams WM; Mabrouk OS; Wong JT; Brake WG; Kennedy RT; du Souich P; Samaha AN;...
The faster drugs of abuse reach the brain, the greater is the risk of addiction. Even small differences in the rate of drug delivery can influence outcome. Infusing cocaine intravenously over 5 vs....
Article GUID: 29757478
Title: | Development of a particle-trap preconcentration-soft ionization mass spectrometric technique for the quantification of mercury halides in air |
Authors: | Deeds DA, Ghoshdastidar A, Raofie F, Guérette ÉA, Tessier A, Ariya PA, |
Link: | https://pubmed.ncbi.nlm.nih.gov/25837315/ |
DOI: | 10.1021/ac504545w |
Category: | Anal Chem |
PMID: | 25837315 |
Dept Affiliation: | MASSSPEC
1 †Department of Atmospheric and Oceanic Sciences, McGill University, Montreal, Quebec H3A 2K6, Canada. 2 ‡Department of Chemistry, McGill University, Montreal, Quebec H3A 2K6, Canada. 3 ?Centre for Biological Applications of Mass Spectrometry, Concordia University, Montreal, Quebec, Canada. |
Description: |
Measurement of oxidized mercury, Hg(II), in the atmosphere poses a significant analytical challenge as Hg(II) is present at ultra-trace concentrations (picograms per cubic meter air). Current technologies are sufficiently sensitive to measure the total Hg present as Hg(II) but cannot determine the chemical speciation of Hg(II). We detail here the development of a soft ionization mass spectrometric technique coupled with preconcentration onto nano- or microparticle-based traps prior to analysis for the measurement of mercury halides in air. The current methodology has comparable detection limits (4-11 pg m(-3)) to previously developed techniques for the measurement of total inorganic mercury in air while allowing for the identification of HgX2 in collected samples. Both mercury chloride and mercury bromide have been sporadically detected in Montreal urban and indoor air using atmospheric pressure chemical ionization-mass spectrometry (APCI-MS). We discuss limitations and advantages of the current technique and discuss potential avenues for future research including quantitative trace measurements of a larger range of mercury compounds. |